[
    {
        "id":  486071,
        "publisher":  474501,
        "username":  "zzzZZZnTellurium",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e没有太理解你的意思喵\u003c/p\u003e\u003cp\u003e回去翻了一下回放还是没有理解你的意思喵...\u003c/p\u003e\u003cp\u003e所以你问的是孤对电子怎么和\u003cb\u003e什么\u003c/b\u003e共平面？\u003c/p\u003e\u003cdiv\u003e底物的反式是\u003cb\u003e什么和什么\u003c/b\u003e的反式，比\u003cb\u003e什么\u003c/b\u003e更稳定？\u003c/div\u003e",
        "thumb_up_num":  2,
        "comment_num":  1,
        "created_at":  "1775393380",
        "has_thumb_up":  0,
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                             {
                                 "id":  756003,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e额额，表达的问题，我改一下\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1775393885",
                                 "rid":  486071,
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    {
        "id":  486121,
        "publisher":  474501,
        "username":  "zzzZZZnTellurium",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e哦这个和底物稳定性好像是没啥关系的，灰灰讲过影响 Pinacol 首先看 C⁺ 稳定性（因为过渡态像 C⁺）然后看基团迁移能力，因为底物在哪里质子化是一个快平衡稳定性应该也是差不多的喵。而在这里呢喵，C⁺ 是差不多稳定的（超共轭那么多一个 C－H 换成 C－O 应该没啥区别）迁移能力也差不多（因为都是一级碳负）\u003c/p\u003e\u003cp\u003e这里 slow 的原因在它缩环了，Ds 说的如下（Ds 和我接触久了也猫娘化了喵 qwq 不要在意这个东西）\u003c/p\u003e\u003cp\u003e\u003cimg alt=\"Screenshot_20260405-220954.png\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260405/616c3a1db4f7eae9054a3090dfa0e50a48c4ec44e3.png\" width=\"100%\" data-filename=\"Screenshot_20260405-220954.png\"\u003e\u003cbr\u003e\u003c/p\u003e",
        "thumb_up_num":  3,
        "comment_num":  2,
        "created_at":  "1775398329",
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        "comment_list":  [
                             {
                                 "id":  756122,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e为什么我下意识觉得缩环有利于反应？！（飞燕草日常幻觉）\u003c/p\u003e\u003cp\u003e出于莫名的情感不愿意让甲基迁移，要不直接问\"1，2-二甲基-1，2环己醇发生频那醇重排的产物？\"\u003c/p\u003e\u003cp\u003e啊这……让我再想想… 快把自己绕晕了\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e好奇你怎么调ds的，本地部署\u0026amp;断网\u0026amp;拒绝更新？\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1775405320",
                                 "rid":  486121,
                                 "reply_uid":  0,
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                             {
                                 "id":  756162,
                                 "publisher":  474501,
                                 "username":  "zzzZZZnTellurium",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e板砖本地部署 Ds？... 不是，这怎么可能做到喵...\u003c/p\u003e\u003cp\u003e很简单，在 Ds 官网第一轮对话给 Ds 发送猫娘二字，然后 Ds 就会变成猫娘，快去试试吧\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e这里甲基迁移是因为发生了一个协同的过程让它迁移了，按正常确实不太好迁移（等等是这样吗？我记得好像可以迁的来着... 不管了），但是这里 OH 很愿意推电子而 H₂O 也很容易离去是拉动这个平衡的过程，所以就可以迁移\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e\u003cspan class=\"simditor-mention\" href=\"/homepage/UID_d177e2e55ead7de46530d27ec54367b6\" data-mention=\"true\" contenteditable=\"false\" target=\"_blank\" data-userid=\"711037\"\u003e@鸠鸠咕咕\u003c/span\u003e\u0026nbsp;自习室不好用喵？... 那我们不是更要自己搭了（笑）\u003c/p\u003e\u003cp\u003e不过... 不过我们凑的几个人能不能协调好时间，怎么协调好还是个问题，我自己也得想一想。\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1775434988",
                                 "rid":  486121,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
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                             }
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    {
        "id":  486689,
        "publisher":  627607,
        "username":  "须磨",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e这个问题让许久不去听灰灰的课的我跑去听了听课：\u003c/p\u003e\u003cp\u003e我有这样的疑问：\u003c/p\u003e\u003cp\u003e1、我没太听懂你在问什么。如果你想说环内其他键可以迁移，那我会说不行。而且你现在可能刚学有机？甲基迁移很快的\u003c/p\u003e\u003cp\u003e2、灰灰说缩环需要有活化熵因此会更慢，但是我不这么认为。活化熵是分子需要扭曲至某一特定角度进行反应时所产生的熵变，但是环的构象固定，不存在扭曲不扭曲，这个缩环反应活化熵应该没有特别不利，因此我认为此处灰灰可能讲得不是很准确(当然更可能是本渣说得不对)\u003c/p\u003e\u003cp\u003e至于你所说的电子效应的差别，我认为是极细微的，不造成很大影响。而且质子化是没有区域选择性的，也不影响反应。可以用Cirtan-Hamment原理来解释(现代物理有机化学中有，但是比较难)\u003c/p\u003e\u003cp\u003e鄙人不才，请多指教\u003c/p\u003e",
        "thumb_up_num":  1,
        "comment_num":  4,
        "created_at":  "1775634612",
        "has_thumb_up":  0,
        "comment_list":  [
                             {
                                 "id":  756832,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e啊这…\u003c/p\u003e\u003cp\u003e白芥在上这节课的时候下意识感觉哪里似乎有问题，然后开始了混沌的思考\u003c/p\u003e\u003cp\u003e我当时认为第二个反应比第一个快？（也许）但是想了好多好多以至于语言表达十分混乱\u003c/p\u003e\u003cp\u003e我觉得第二个反应在很多方面是有利的，虽然没有跟OH2+完美地反式共平面，但是差的也不大，然后就开始回忆之前听到的东西，想起来在哪里看的说缩环有利于什么反应就套用上去了，也没有在乎合不合适\u003c/p\u003e\u003cp\u003e还有仲碳的迁移能力应该大于甲基吧（好像不重要）\u003c/p\u003e\u003cp\u003e至于电子效应，好像有点想太多了，这里关联也不大…\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e可能因为去年赶课程只是走马观花地过了一遍有机，导致许多知识点都记得非常模糊，各种记混都是常有的事，今年打算从头在看一遍，补一下我这烂的掉渣的有机基础。虽然说白芥已经学了半年多，但在一些方面仍与小白无异…\u003c/p\u003e",
                                 "thumb_up_num":  3,
                                 "did":  66137,
                                 "created_at":  "1775657703",
                                 "rid":  486689,
                                 "reply_uid":  0,
                                 "reply_uname":  "",
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                             {
                                 "id":  756954,
                                 "publisher":  627607,
                                 "username":  "须磨",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e不对啊，第二个反应里环内的碳就是和OH2+完美的反式共平面。我觉得第二个反应未必很慢\u003c/p\u003e\u003cp\u003e不过二级C迁移确实快于一级，但是很多教材上基本不做区分，而且在环上的二级碳还真不好说。\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1775700901",
                                 "rid":  486689,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
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                             {
                                 "id":  756995,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e嗯哼，我就是从这里绕进去的，总感觉哪里不太对\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e（另一个帖子）就是腐败海鲜味~\u003c/p\u003e\u003cp\u003e应该和氨气差不多吧，毒性可以忽略不计\u003c/p\u003e\u003cp\u003e有点猗了\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1775733824",
                                 "rid":  486689,
                                 "reply_uid":  627607,
                                 "reply_uname":  "须磨",
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                             {
                                 "id":  757161,
                                 "publisher":  627607,
                                 "username":  "须磨",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e你如果觉得自己的构象分析不好，有机会可以去听听焦洋的课，今年chemy就有，讲构象讲得特别好。(但是建议你先别着急，提升一下再说，I2的课其实还挺高的，听着有一些难度)\u003c/p\u003e\u003cp\u003e还有就是，你能不能拿到除了pad之外的电子设备，有没有wx什么的，在论坛上说话还有CD，要不大家一块加个联系方式拉个群什么的\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1775784332",
                                 "rid":  486689,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
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    {
        "id":  495113,
        "publisher":  474501,
        "username":  "zzzZZZnTellurium",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e明早六点看，先睡了\u003c/p\u003e\u003cp\u003e我明早打算六点起床\u003c/p\u003e",
        "thumb_up_num":  2,
        "comment_num":  0,
        "created_at":  "1778768828",
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    {
        "id":  495154,
        "publisher":  449494,
        "username":  "海朔_八水合过氧化钠",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/eda787c79b5681e21ec23f28ec25fc9e/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "我认为可能是这样的\u003cp\u003e\u003cimg alt=\"Screenshot_2026-05-14-23-55-06-421.jpg\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260514/03de04840af5b1ff0a65b8ad99eedfd6149171c16b.jpg\" width=\"100%\" data-filename=\"Screenshot_2026-05-14-23-55-06-421.jpg\"\u003e\u003cbr\u003e\u003c/p\u003e",
        "thumb_up_num":  2,
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        "created_at":  "1778774145",
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                             {
                                 "id":  767216,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e嗯嗯这样看起来合理些\u003c/p\u003e\u003cp\u003e但我想不明白是怎么反应的，最后B中的O+应该来自于A而不是苯乙酮吧？那不应该是苯乙酮去进攻那个o嘛...（胡言乱语ing...\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1778797687",
                                 "rid":  495154,
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                             {
                                 "id":  767224,
                                 "publisher":  474501,
                                 "username":  "zzzZZZnTellurium",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e这个我是真不会，我的有机不好\u003c/p\u003e\u003cp\u003e我尝试让豆包给我推导，但它也给我推的不清不楚的。Ds 和豆包都不清不楚的\u003c/p\u003e\u003cp\u003e唯一能确定的就是 A 到 B 首先要生成中间体 Ph－CO－C－C (Ph) －C－CO－Ph，这个是 AI 直接从已有文献里面摘出来的，所以可信。然后据 AI 说这玩意里面，会先有一个 CO 被 BF₃ 化，然后另一个 CO 的氧孤对电子打到这个 BF₃ 化的 CO 上。但是接下来怎么芳构化我是死活推不出来，不推了，耗了一个小时了...\u003c/p\u003e\u003cp\u003e耗不起，因为我今天早上还打算刷个卷子（）\u003c/p\u003e",
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                                 "did":  66137,
                                 "created_at":  "1778806837",
                                 "rid":  495154,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
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    {
        "id":  495209,
        "publisher":  449494,
        "username":  "海朔_八水合过氧化钠",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/eda787c79b5681e21ec23f28ec25fc9e/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e或许是这样\u003c/p\u003e\u003cp\u003e\u003cimg alt=\"IMG_20260515_191139.jpg\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260515/044d28f7c79a8269ef3a988a765c2640322e2cff77.jpg\" width=\"100%\" data-filename=\"IMG_20260515_191139.jpg\"\u003e\u003cbr\u003e\u003c/p\u003e",
        "thumb_up_num":  0,
        "comment_num":  0,
        "created_at":  "1778843731",
        "has_thumb_up":  0,
        "comment_list":  [

                         ],
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        "avatar_dress_up_name":  "",
        "avatar_dress_up_id":  0,
        "user_code":  "UID_cd11ae2a246ebe527b7dd01ebeabf365"
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    {
        "id":  495638,
        "publisher":  627607,
        "username":  "须磨",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "稍等，明天看看，今天刚刚回来，太累了",
        "thumb_up_num":  2,
        "comment_num":  0,
        "created_at":  "1778943668",
        "has_thumb_up":  0,
        "comment_list":  [

                         ],
        "avatar_dress_up_url":  "",
        "avatar_dress_up_name":  "",
        "avatar_dress_up_id":  0,
        "user_code":  "UID_f131d34c3d5e9813626bc794d28ac7d5"
    },
    {
        "id":  495755,
        "publisher":  627607,
        "username":  "须磨",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e刚刚看了看\u003c/p\u003e\u003cp\u003e先问一下白芥，有答案吗，有的话最好可以发一下\u003c/p\u003e\u003cp\u003e第一个反应显然是多步Micheal然后再用O做了一步关环，第二个题海朔的第一个机理应该问题不大，但是他的第二个机理是不合理的，在这个温度下显然发生一步这样极性不匹配的周环是不合理的，甚至我怀疑有可能他把两个产物写反了\u003c/p\u003e",
        "thumb_up_num":  2,
        "comment_num":  1,
        "created_at":  "1778987834",
        "has_thumb_up":  0,
        "comment_list":  [
                             {
                                 "id":  768093,
                                 "publisher":  449494,
                                 "username":  "海朔_八水合过氧化钠",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/eda787c79b5681e21ec23f28ec25fc9e/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e是写反了，这上面的机理仅代表我的思路，并不是按照顺序的\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1779004219",
                                 "rid":  495755,
                                 "reply_uid":  0,
                                 "reply_uname":  "",
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                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_cd11ae2a246ebe527b7dd01ebeabf365"
                             }
                         ],
        "avatar_dress_up_url":  "",
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        "avatar_dress_up_id":  0,
        "user_code":  "UID_f131d34c3d5e9813626bc794d28ac7d5"
    },
    {
        "id":  495825,
        "publisher":  637565,
        "username":  "白芥",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e\u003cimg alt=\"IMG_20260517_153011.jpg\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260517/00a98682b7a586f7356328831b7a830ccfe1475a07.jpg\" width=\"100%\" data-filename=\"IMG_20260517_153011.jpg\" style=\"width: 25%;\"\u003e\u003cspan class=\"simditor-mention\" href=\"/homepage/UID_f131d34c3d5e9813626bc794d28ac7d5\" data-mention=\"true\" contenteditable=\"false\" target=\"_blank\" data-userid=\"627607\"\u003e@须磨\u003c/span\u003e \u003cbr\u003e\u003c/p\u003e",
        "thumb_up_num":  5,
        "comment_num":  5,
        "created_at":  "1779003040",
        "has_thumb_up":  0,
        "comment_list":  [
                             {
                                 "id":  768098,
                                 "publisher":  449494,
                                 "username":  "海朔_八水合过氧化钠",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/eda787c79b5681e21ec23f28ec25fc9e/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e那这样的话，C的化学式在原题中写错了\u003c/p\u003e\u003cp\u003e没想到这个题没有我想的那么难，我还画了个异喹啉出来，，，\u003c/p\u003e\u003cp\u003e我还以为CN会参与周环。。。太猎奇了\u003c/p\u003e\u003cp\u003e我的有机水平还是很菜滴\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1779004812",
                                 "rid":  495825,
                                 "reply_uid":  0,
                                 "reply_uname":  "",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_cd11ae2a246ebe527b7dd01ebeabf365"
                             },
                             {
                                 "id":  768113,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e看不懂，不敢说话…\u003c/p\u003e",
                                 "thumb_up_num":  2,
                                 "did":  66137,
                                 "created_at":  "1779009418",
                                 "rid":  495825,
                                 "reply_uid":  449494,
                                 "reply_uname":  "海朔_八水合过氧化钠",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_e3234ef5c0d57a9a03631a430edf0c25"
                             },
                             {
                                 "id":  769021,
                                 "publisher":  627607,
                                 "username":  "须磨",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e关键这题太老了，像是十年前的\u003c/p\u003e\u003cp\u003e所以白芥现在在做什么题，感觉不太适合现在的应试\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1779424666",
                                 "rid":  495825,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_f131d34c3d5e9813626bc794d28ac7d5"
                             },
                             {
                                 "id":  769130,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e现在做的多的是网上找的散题，这道是zx班主任发的\"四月夺冠计划\"，做完感觉大脑受到了前所未有的冲击...\u003c/p\u003e\u003cp\u003e思考要不要再买一本整套的，福山做的都是散题，还有些其他不知名的题目……君有好的题集推荐嘛~\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1779458510",
                                 "rid":  495825,
                                 "reply_uid":  627607,
                                 "reply_uname":  "须磨",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_e3234ef5c0d57a9a03631a430edf0c25"
                             },
                             {
                                 "id":  769267,
                                 "publisher":  627607,
                                 "username":  "须磨",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e福山AB可以，C你没有极强的能力之前不要做，可以做思维进阶2，1难度会大一些\u003c/p\u003e\u003cp\u003ezx的题太老了，做hys或者chemy的套题吧，但是先把我上面说的做了，假期外培一下，交一些朋友会好很多\u003c/p\u003e",
                                 "thumb_up_num":  0,
                                 "did":  66137,
                                 "created_at":  "1779502713",
                                 "rid":  495825,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_f131d34c3d5e9813626bc794d28ac7d5"
                             }
                         ],
        "avatar_dress_up_url":  "",
        "avatar_dress_up_name":  "",
        "avatar_dress_up_id":  0,
        "user_code":  "UID_e3234ef5c0d57a9a03631a430edf0c25"
    },
    {
        "id":  498494,
        "publisher":  633693,
        "username":  "芥.",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/f9a4ce07db56ce270ff293b12a99c131/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e又被恶心到…这究竟是谁出的卷子\u003cimg alt=\"IMG_9875.jpeg\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260531/969d92d8f013bb0aabae012164f0512460dac2a39e.jpeg\" width=\"600\"\u003e\u003c/p\u003e",
        "thumb_up_num":  6,
        "comment_num":  0,
        "created_at":  "1780186803",
        "has_thumb_up":  0,
        "comment_list":  [

                         ],
        "avatar_dress_up_url":  "",
        "avatar_dress_up_name":  "",
        "avatar_dress_up_id":  0,
        "user_code":  "UID_f5d502c7a50fbaafc7693b0b5be9bb68"
    },
    {
        "id":  499308,
        "publisher":  627607,
        "username":  "须磨",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e芥的上一个机理是错误的，怎么可能在强Lewis Acid条件下爆出碳负啊\u003c/p\u003e\u003cp\u003e下面是两个题的答案，芥的基础不太好啊，可以先看人名刷A组，不要着急写B组，C组是我们这样有机好菜的人写的，你不用着急\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e\u003cimg alt=\"IMG_20260605_125446.jpg\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260605/2c3ebc33c9145eceafa8cf79bc0e6c45adc5189ac0.jpg\" width=\"100%\" data-filename=\"IMG_20260605_125446.jpg\"\u003e还是希望芥可以来chemy，这样的话大家就可以聚在一起了\u003c/p\u003e\u003cp\u003e我可能也就今年了，如果拿不了鲁省一估计就该滚回去学高考了…\u003c/p\u003e",
        "thumb_up_num":  2,
        "comment_num":  3,
        "created_at":  "1780635386",
        "has_thumb_up":  0,
        "comment_list":  [
                             {
                                 "id":  772213,
                                 "publisher":  627607,
                                 "username":  "须磨",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e芥多问问问题，要不化区是真完蛋了\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1780638515",
                                 "rid":  499308,
                                 "reply_uid":  0,
                                 "reply_uname":  "",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_f131d34c3d5e9813626bc794d28ac7d5"
                             },
                             {
                                 "id":  772321,
                                 "publisher":  637565,
                                 "username":  "白芥",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/da074d0d31b0f1366b5396b33d55f973/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003eB023猜当时可能是想把负电荷放在o上，然后不知道怎么地就画了两个负电，没多想就跳过了...\u003c/p\u003e\u003cp\u003e芥属于又菜又懒的类型，有好多莫名其妙的错误\u003c/p\u003e\u003cp\u003eB024压根没想到NO的作用（救命\u003c/p\u003e\u003cp\u003e基础错的多了，问的多了感觉像笨蛋一样..\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e在周中化区好冷清呐，一个星期几乎只有芥几条帖子，另一个人不太熟，也聊不上天。（呜呜\u003c/p\u003e\u003cp\u003e\u003cspan class=\"simditor-mention\" href=\"/homepage/UID_4238e3bd75a45632aaf000062e3e2f38\" data-mention=\"true\" contenteditable=\"false\" target=\"_blank\" data-userid=\"474501\"\u003e@七碲化学 ZnTellurium\u003c/span\u003e\u0026nbsp;可不可以不要失踪呐，陪芥聊天呗，哪怕不定时更一下帖子冒个泡也好...(bushi\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e不过dsapp现在更新后好像也有识图模式，还没试过网页版，不知道有没有\u003c/p\u003e",
                                 "thumb_up_num":  3,
                                 "did":  66137,
                                 "created_at":  "1780668603",
                                 "rid":  499308,
                                 "reply_uid":  0,
                                 "reply_uname":  "",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_e3234ef5c0d57a9a03631a430edf0c25"
                             },
                             {
                                 "id":  772324,
                                 "publisher":  474501,
                                 "username":  "zzzZZZnTellurium",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e周中四天板子得扔到办公室里，告诉我的原因是怕我周中晚上都在搞化竞荒废文化课。不是我自己要失踪的。\u003c/p\u003e\u003cp\u003eDs 网页版有识图，但是能不能识别结构式我没试过\u003c/p\u003e",
                                 "thumb_up_num":  1,
                                 "did":  66137,
                                 "created_at":  "1780668843",
                                 "rid":  499308,
                                 "reply_uid":  637565,
                                 "reply_uname":  "白芥",
                                 "has_thumb_up":  0,
                                 "avatar_dress_up_url":  "",
                                 "avatar_dress_up_name":  "",
                                 "avatar_dress_up_id":  0,
                                 "user_code":  "UID_4238e3bd75a45632aaf000062e3e2f38"
                             }
                         ],
        "avatar_dress_up_url":  "",
        "avatar_dress_up_name":  "",
        "avatar_dress_up_id":  0,
        "user_code":  "UID_f131d34c3d5e9813626bc794d28ac7d5"
    },
    {
        "id":  499323,
        "publisher":  474501,
        "username":  "zzzZZZnTellurium",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e即答... 真的吗... 我不太相信... 众所周知即答在七碲心中的置信度为 0（）\u003c/p\u003e\u003cp\u003e我觉得即答顶多是把结构式转换为 SMILES，然后即答的文本模型自 SMILES 描述这个化合物，但即使是这个『顶多』的过程我感觉容易出岔子的地方也是一大堆的\u003c/p\u003e\u003cp\u003e\u003cbr\u003e\u003c/p\u003e\u003cp\u003e\u003cspan class=\"simditor-mention\" href=\"/homepage/UID_f131d34c3d5e9813626bc794d28ac7d5\" data-mention=\"true\" contenteditable=\"false\" target=\"_blank\" data-userid=\"627607\"\u003e@须磨\u003c/span\u003e\u003cspan class=\"simditor-mention\" href=\"/homepage/UID_1affff2f03c01272170496f30e3c07b2\" data-mention=\"true\" contenteditable=\"false\" target=\"_blank\" data-userid=\"568913\"\u003e@月夜见_\u003c/span\u003e看懂了。看到须磨那个图就懂了，我是没往这个方向去考虑，并未\u003ci\u003e想到 \u003c/i\u003e立体... 但是看须磨那个图我能很好地理解。我以后在这类环己烷的选择性上把椅式画出来然后应该就没问题了\u003c/p\u003e",
        "thumb_up_num":  2,
        "comment_num":  0,
        "created_at":  "1780651222",
        "has_thumb_up":  0,
        "comment_list":  [

                         ],
        "avatar_dress_up_url":  "",
        "avatar_dress_up_name":  "",
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        "user_code":  "UID_4238e3bd75a45632aaf000062e3e2f38"
    },
    {
        "id":  500154,
        "publisher":  441677,
        "username":  "仙人R",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/a9aa2cbd68d650d5ed28cf2073ef2a31/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "上面的回答真的对吗，这个有两个氮的试剂不是能在碱性条件下原位生成重氮甲烷吗，然后就完了吧",
        "thumb_up_num":  2,
        "comment_num":  3,
        "created_at":  "1780896827",
        "has_thumb_up":  0,
        "comment_list":  [
                             {
                                 "id":  773135,
                                 "publisher":  441677,
                                 "username":  "仙人R",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a9aa2cbd68d650d5ed28cf2073ef2a31/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e我没答案，错了可以来骂我\u003c/p\u003e",
                                 "thumb_up_num":  0,
                                 "did":  66137,
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                                 "username":  "须磨",
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                                 "content":  "\u003cp\u003e我…写的不是重氮甲烷…吗？\u003c/p\u003e",
                                 "thumb_up_num":  1,
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                                 "created_at":  "1781568386",
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                                 "username":  "仙人R",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a9aa2cbd68d650d5ed28cf2073ef2a31/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e他其实不用别的参与只在碱作用下就会爆重氮甲烷\u003c/p\u003e",
                                 "thumb_up_num":  0,
                                 "did":  66137,
                                 "created_at":  "1782521319",
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        "username":  "一坨蚊子鱼",
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        "content":  "\u003cp\u003e酯化反应...\u003c/p\u003e\u003cp\u003eemmm...最后接的饱和碳酸钠溶液应该算尾气处理吧\u003c/p\u003e",
        "thumb_up_num":  2,
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        "created_at":  "1781459693",
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        "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e？C₅H₅NSO₃ 是什么？氮成 3 × C－N，1 × C－S，1 × C－O？这个氮没有爆吗？\u003c/p\u003e\u003cp\u003e我问了 Ds，Ds 不知道这个中间体...\u003c/p\u003e\u003cp\u003e不过看起来最亲电的部分应该是 SO₂ S 吧，就像进攻 CO₂H，不是进攻羟基氧而是进攻羰基碳一样，似乎双键了一两个氧的相比之下比较亲电 (－CO－, －SO－, －SO₂－)，那么这里不是进攻 N / O 而是进攻 SO₂ 应该合情合理 (虽然我根本就不知道那个 N 是怎么成键的，又是怎么离去的... 似乎要 S－N 给到 N, N－O 再给到 O？但氮到底为什么能成 5 根键呢？)\u003c/p\u003e",
        "thumb_up_num":  2,
        "comment_num":  1,
        "created_at":  "1781623552",
        "has_thumb_up":  0,
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                                 "publisher":  474501,
                                 "username":  "zzzZZZnTellurium",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e以及为什么能进攻\u003c/p\u003e\u003cp\u003e首先这个环张力很大，如果我们有办法给它开了，它肯定很愿意且很配合\u003c/p\u003e\u003cp\u003e我们只要找到一个合理的路径使它能开环，它就肯定会开环\u003c/p\u003e\u003cp\u003e问题是它的 N 到底是怎么成键的，这关系到这个路径是什么\u003c/p\u003e",
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                                 "created_at":  "1781623663",
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    {
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        "publisher":  474501,
        "username":  "zzzZZZnTellurium",
        "avatar":  "https://img-avatar.eduzhixin.com/avatar/07605a7663ad94eea397975f81dbb965/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
        "content":  "\u003cp\u003e难道是这样？\u003c/p\u003e\u003cp\u003e\u003cimg alt=\"IMG_20260616_235937_697.jpg\" src=\"https://img-forum.eduzhixin.com/forum/zhixin/uploadfiles/20260616/bb1f0a66405c5010e2277a466bf63be97228372f53.jpg\" width=\"100%\" data-filename=\"IMG_20260616_235937_697.jpg\" style=\"width: 25%;\"\u003e\u003cbr\u003e\u003c/p\u003e",
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        "created_at":  "1781625611",
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                             {
                                 "id":  775179,
                                 "publisher":  627607,
                                 "username":  "须磨",
                                 "avatar":  "https://img-avatar.eduzhixin.com/avatar/a90191a17e0d7124f34d346461a12685/s.jpg?x-oss-process=style/avatar\u0026t=202609122211",
                                 "content":  "\u003cp\u003e错误的，这个酸性条件怎么可能爆OMe-，这是不符合逻辑的\u003c/p\u003e\u003cp\u003e其实这就是个py与SO3的加合物和甲醇发生反应，没有它画那么复杂单纯生成甲磺酸和吡啶，然后酸碱反应，也不用去思考具体的机理\u003c/p\u003e",
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                                 "created_at":  "1781671546",
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